We achieved copper-catalyzed intramolecular and intermolecular alkoxylation of azoles. This reaction is a rare example of transition-metal-catalyzed C–H alkoxylation of heteroaromatic compounds. In ...

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† State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China ‡ State Key Laboratory of Organometallic Chemistry, Shanghai ...